| Annie Chemie P Ltd is engaged in manufacture of Shale Gas Fracturing Chemicals. Ammonium Persulfate, Potassium Persulphate & Sodium Bromate based Encapsulated Gel Breaker for Guar is offered. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of Encapsulated Gel Breaker is in these pages. |
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Low & High Temperature Encapsulated Ammonium Persulfate Gel Breaker Manufacturers SDS of Exporters
Specifications of Encapsulated Ammonium Persulfate Gel Breaker Manufacturers
Encapsulated Gel Breaker Ammonium Persulfate Based SDS, Safety Data Sheet
MSDS
1. Product Identification
Product Name/Synonyms: Encapsulated Ammonium Persulfate, Coated Gel Breaker, Encapsulated Breaker LT, Encapsulated Breaker HT, Encapsulated Breaker MT.
Intended Use: Oil & Gas Exploration. Breaking of Gaur Gum Gel in Oil well drilling fracking or fracturing.
Molecular Weight: Not applicable
Chemical Formula: Not applicable
Intended Use and uses advised against (if any): Oil & Gas Wells fracturing and Industrial Manufacturing.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Oxidizing Solids Category 3, H272
Acute toxicity - Oral Category 4, H302
Skin corrosion/irritation Category 2, H315
Skin sensitization Category 1, H317
Serious eye damage/eye irritation Category 2A, H319
Respiratory sensitization Category 1, H334
Specific target organ toxicity (single exposure), Respiratory tract Category 3, H335
Labeling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements  Oxidizer |
GHS Label Elements |
GHS Label Elements |
Signal Words: Warning
Hazard Statements:
H272: May intensify fire; oxidizer
H302: Harmful if swallowed
H315 : Causes skin irritation
H317: May cause an allergic skin reaction
H319: Causes serious eye irritation
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335: May cause respiratory irritation.
Precautionary Statements - Prevention:
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray
P264: Wash ... thoroughly after handling
P270: Do not eat, drink or smoke when using this product
P271: Use only outdoors or in a well-ventilated area.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P285: In case of inadequate ventilation wear respiratory protection.
Precautionary Statements - Response:
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P304 + P341: IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P332+P313: If skin irritation occurs: Get medical advice/attention
P337+P313: If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P362: Take off contaminated clothing and wash before reuse.
Precautionary Statements - Storage
P402: Store in a dry place
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P501: Dispose of contents/container to authorized agents only.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
O Oxidizing
Xn Harmful
Xi Irritant
Risk Phrase:
R8- Contact with combustible material may cause fire.
R22 Harmful if swallowed.
R36/37/38 Irritating to eyes, respiratory system, and skin.
R42 May cause sensitization by inhalation.
R43 May cause sensitization by skin contact.
3. Composition/Information on Ingredients
1. Ammonium Persulfate
CAS Number: 7727-54-0
EC Number: 231-786-5
Less than 90%
2. Other Non-Haz Ingredients
Less than 25%
Confidential Business Information.
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing & shoes before reuse. Get medical attention.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire: Ammonium Persulfate and Encapsulated Gel Breaker is not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Heating or contact with water releases oxygen which may intensify combustion in an existing fire.
Explosion: An explosion hazard when mixed with finely powdered organic matter, metal powder, or reducing agents.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Do not use water.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
6. Accidental Release Measures
Personal precautions, protective equipment, environmental precautions and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material. Keep away from drains, surface and groundwater and soil.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible, inorganic absorbent material, sweep up, and remove to an approved disposal container.
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: It is an oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep the substance damp using water spray. Do not touch spilled material. Prevent entry into sewers. Eliminate all ignition sources. Avoid penetration into waterways, sewers, soil or groundwater.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices with proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Prevent any contact with hot surfaces. Containers of this material may be hazardous when empty since they retain product residues.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like combustibles, organic or other readily oxidizable materials. Avoid storage on wood floors. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Handle product only in closed system or provide appropriate exhaust ventilation at machinery.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: - ACGIH Threshold Limit Value (TLV): 0.1 mg/m3 (TWA) as persulfate
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards.
9. Physical and Chemical Properties
Appearance: Encapsulate Gel Breaker is white to off-white crystals
Odor: Mild organic odor
Odor threshold: Not available.
pH: Not available.
Relative density: 1.75
Melting Point: Decomposes
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: Soluble in water.
Viscosity: No data found.
10. Stability and Reactivity
Stability: It is stable under ordinary conditions of use and storage. Stability decreases in the presence of moisture
Hazardous Decomposition Products: Decomposed by moisture to form oxygen and ozone. Burning may produce nitrogen oxides, sulfur oxides, sulfuric acid, chlorine or hydrochloric acid and fumes.
Hazardous Polymerization: Will not occur
Incompatibilities: Reducing agents, organic material, sodium peroxide, water and powdered metals especially aluminum
Conditions to Avoid: Moisture, combustible materials and incompatibles.
11. Toxicological Information
Ammonium Persulfate: Oral rat LD50: 689 mg/kg
Carcinogenic Effects: Not known to be a carcinogen.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
12. Ecological Information
Environmental Toxicity: No information found.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with legal requirements.
14. Transport Information
Domestic Land, DOT USA & ADR/RID Europe
UN/NA: UN1444
Proper Shipping Name: Contains Ammonium Persulfate
Hazard Class: 5.1; Packing Group: III
International (Water, I.M.O.)
UN/NA: UN1444
Proper Shipping Name: Contains Ammonium Persulfate
Hazard Class: 5.1; Packing Group: III
15. Regulatory Information
USA:
California No Significant Risk Level: None of the chemicals in this product are listed.
Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H272: May intensify fire; oxidizer
H302: Harmful if swallowed
H315 : Causes skin irritation
H317: May cause an allergic skin reaction
H319: Causes serious eye irritation
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335: May cause respiratory irritation
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Low & High Temperature Encapsulated Ammonium Persulfate Gel Breaker Manufacturers Suppliers Exporters:
Annie Chemie P Ltd.
Offered from UAE, USA and Gujarat-India.
TELEPHONE: (OFFICE) 91-22-23770100, 23726950; FAX: 91-22-23728264
Between 5 Hour GMT to 12 Hour GMT
e-mail: info@anniechemie.com
Last updated: January 17, 2022
Exporters to USA Canada UAE Europe Russia China, South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai etc.